The mass of the air sample is calculated using the below
Q(heat)=M(mass) x C(specific heat capacity) x delta T(change in temperature)
Q= 120.j
M=?
C= 1.0j/g/c
delta T =45.0-33.2=11.8 c
by making M the subject of the formula
M=Q/C delta T
= 120 j/ 1.0 j/g/c x11.8 c=10.17 grams