although scandium is a member of the d block, its ion (Sc3+) hasn't got any d electrons left to move around. This is no different from an ion based on Mg2+ or Al3+. Scandium(III) complexes are colourless because no visible light is absorbed.In the zinc case, the 3d level is completely full - there aren't any gaps to promote an electron in to. Zinc complexes are also colourless.So thats why it be handy to know the colors associated with different oxidation states of certain ions