When 1.025 g of naphthalene (c10h8) burns in a bomb calorimeter, the temperature rises from 24.25°c to 32.33°c. find δerxn for the combustion of naphthalene. the heat capacity of the calorimeter is 5.11 kj/°c?

Respuesta :

Answer : The [tex]\Delta E[/tex] for the combustion of naphthalene is [tex]5161.25KJ/mole[/tex]

Solution : Given,

Mass of naphthalene = 1.025 g

Initial temperature = [tex]24.25^oC[/tex]

Final temperature = [tex]32.33^oC[/tex]

Specific heat capacity of calorimeter = [tex]5.11KJ/^oC[/tex]

Molar mass of naphthalene = 128 g/mole

First, we have to calculate the heat absorbed, [tex]q[/tex]

Formula used :

[tex]q=c\times \Delta T=c\times (T_{final}-T_{initial})[/tex]

Now put all the given values in this formula, we get

[tex]q=(5.11KJ/^oC)\times (32.33^oCT-24.25^oC)=41.29KJ[/tex]

Now we have to calculate the moles of naphthalene.

Moles of [tex]C_{10}H_{8}[/tex] = [tex]\frac{\text{ Mass of }C_{10}H_{8}}{\text{ Molar mass of }C_{10}H_{8}}=\frac{1.025g}{128g/mole}=0.0080moles[/tex]

Now we have to calculate the [tex]\Delta E[/tex] for combustion of naphthalene.

[tex]\Delta E=\frac{q}{n}[/tex]

where,

q = heat absorbed

n = number of moles

Now put all the values in this formula, we get

[tex]\Delta E=\frac{41.29KJ}{0.0080moles}=5161.25KJ/mole[/tex]

Therefore, the [tex]\Delta E[/tex] for the combustion of naphthalene is [tex]5161.25KJ/mole[/tex]