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How do the interactions that are broken in water when it is boiled compare with those broken when water is electrolyzed? Boiling water breaks intermolecular attractions and electrolysis breaks covalent bonds. Boiling water breaks covalent bonds and electrolysis breaks intermolecular attractions. Boiling water and electrolysis of water break covalent bonds. Boiling water and electrolysis of water break intermolecular forces.