A mysterious compoud with the chemical formula MX (Ksp 1.27x10-36) is present in two different solutions. What is its molar solubility in 0.25 M M2SO4?

Respuesta :

Answer: The molar solubility of MX is [tex]2.54\times 10^{-36}M[/tex]

Explanation:

We are given:

[tex]K_{sp}(MX)=1.27\times 10^{-36}[/tex]

The chemical equation for the ionization of MX follows:

[tex]MX\rightleftharpoons M^+(aq.)+X^-(aq.)[/tex]

                  S         S

The expression of [tex]K_{sp}[/tex] for above equation is:

[tex]K_{sp}=S\times S[/tex]      ......(1)

The chemical equation for the ionization of [tex]M_2SO_4[/tex] follows:

[tex]M_2SO_4\rightleftharpoons 2M^+(aq.)+SO_4^{2-}(aq.)[/tex]

 0.25M           0.5M      0.25M

Total concentration of cation from both the equation is:

[tex][M^+]=0.5+S[/tex]

As, [tex]K_{sp}(MX)<<1[/tex], so S is also very very less than 1 and can be easily neglected.

So, [tex][M^+]=0.5M[/tex]

Putting values in equation 1, we get:

[tex]1.27\times 10^{-36}=0.5\times S\\\\S=2.54\times 10^{-36}M[/tex]

Hence, the molar solubility of MX is [tex]2.54\times 10^{-36}M[/tex]