Indicate the concentration of each ion or molecule present in the following solutions: (a) 0.25 M NaNO3, ( b ) 1.3 * 10-2 M MgSO4, ( c ) 0.0150 M C6H12O6, (d) a mixture of 45.0 mL of 0.272 M NaCl and 65.0 mL of 0.0247 M 1NH422CO3. Assume that the volumes are additive.

Respuesta :

Answer:

For a: The concentration of sodium and nitrate ions are 0.25 M and 0.25 M respectively.

For b: The concentration of magnesium and sulfate ions are [tex]1.3\times 10^{-2}M[/tex] and [tex]1.3\times 10^{-2}M[/tex] respectively.

For c: The concentration of glucose solution is 0.0150 M

For d: The concentration of sodium, chloride, ammonium and carbonate ions in the mixture are 0.111 M, 0.111 M, 0.0146 M and 0.0146 M respectively.

Explanation:

  • For a:  0.25 M [tex]NaNO_3[/tex]

The chemical equation for the ionization of sodium nitrate follows:

[tex]NaNO_3\rightarrow Na^++NO_3^-[/tex]

1 mole of sodium nitrate produces 1 mole of sodium ions and 1 mole of nitrate ions

Concentration of sodium ions = 0.25 M

Concentration of nitrate ions = 0.25 M

Hence, the concentration of sodium and nitrate ions are 0.25 M and 0.25 M respectively.

  • For b:  [tex]1.3\times 10^{-2}M[/tex] of [tex]MgSO_4[/tex]

The chemical equation for the ionization of magnesium sulfate follows:

[tex]MgSO_4\rightarrow Mg^{2+}+SO_4^{2-}[/tex]

1 mole of magnesium sulfate produces 1 mole of magnesium ions and 1 mole of sulfate ions

Concentration of magnesium ions = [tex]1.3\times 10^{-2}M[/tex]

Concentration of sulfate ions = [tex]1.3\times 10^{-2}M[/tex]

Hence, the concentration of magnesium and sulfate ions are [tex]1.3\times 10^{-2}M[/tex] and [tex]1.3\times 10^{-2}M[/tex] respectively.

  • For c:  0.0150 M [tex]C_6H_{12}O_6[/tex]

The given compound is a covalent compound and will not dissociate into its respective ions. So, the only chemical species present in the solution is [tex]C_6H_{12}O_6[/tex]

Hence, the concentration of glucose solution is 0.0150 M

  • For d: A mixture of 45.0 mL of 0.272 M NaCl and 65.0 mL of 0.0247 M [tex](NH_4)_2CO_3[/tex]

To calculate the number of moles for given molarity, we use the equation:

[tex]\text{Molarity of the solution}=\frac{\text{Moles of solute}\times 1000}{\text{Volume of solution (in mL)}}[/tex]     .....(1)

For sodium chloirde:

Molarity of NaCl solution = 0.272 M

Volume of solution = 45.0 mL

Putting values in equation 1, we get:

[tex]0.272M=\frac{\text{Moles of NaCl}\times 1000}{45}\\\\\text{Moles of NaCl}=\frac{0.272\times 45}{1000}=1.22\times 10^{-2}mol[/tex]

For ammonium carbonate:

Molarity of ammonium carbonate solution = 0.0247 M

Volume of solution = 65.0 mL

Putting values in equation 1, we get:

[tex]0.0247M=\frac{\text{Moles of ammonium carbonate}\times 1000}{65}\\\\\text{Moles of ammonium carbonate}=\frac{0.0247\times 65}{1000}=1.61\times 10^{-3}mol[/tex]

Total volume of the solution = 45 + 65 = 110 mL

Molarity of NaCl in the mixture = [tex]\frac{1.22\times 10^{-2}mol\times 1000}{110}=0.111M[/tex]

Molarity of ammonium carbonate in the mixture = [tex]\frac{1.61\times 10^{-3}mol\times 1000}{110}=0.0146M[/tex]

The chemical equation for the ionization of sodium chloride follows:

[tex]NaCl\rightarrow Na^{+}+Cl^{-}[/tex]

1 mole of sodium chloride produces 1 mole of sodium ions and 1 mole of chloride ions

Concentration of sodium ions = 0.111 M

Concentration of chloride ions = 0.111 M

The chemical equation for the ionization of ammonium carbonate follows:

[tex](NH_4)_2CO_3\rightarrow 2NH_4^{+}+CO_3^{2-}[/tex]

1 mole of ammonium carbonate produces 1 mole of ammonium ions and 1 mole of carbonate ions

Concentration of ammonium ions = 0.0146 M

Concentration of carbonate ions = 0.0146 M

Hence, the concentration of sodium, chloride, ammonium and carbonate ions in the mixture are 0.111 M, 0.111 M, 0.0146 M and 0.0146 M respectively.

A) The concentration of each ion is;

Concentration of Na⁺ = 0.25 M

Concentration of NO₃⁻ = 0.25 M

B) The concentration of each ion is;

Concentration of Mg²⁺ = 1.3 × 10⁻² M

Concentration of SO₄²⁻ = 1.3 × 10⁻² M

C) Concentration remains 0.015 M.

D) The concentration of each ion is;

Concentration of Na⁺ = 0.111 M

Concentration of Cl⁻ = 0.111 M

Concentration of NH₄⁺ = 0.0146 M

Concentration of CO₃⁻² = 0.0292 M

A) We are given the solution NaNO₃.

Its' molarity = 0.25 M

To know the concentration of each ion or molecule present, we have to write its' ionization equation first;

NaNO₃ → Na⁺ + NO₃⁻

Now, the equation is balanced and we can see that;

1 mole of NaNO₃  produces 1 mole of Na⁺ and 1 mole of NO₃⁻.

Thus;

Concentration of Na⁺ = 0.25 M

Concentration of NO₃⁻ = 0.25 M

B) We are given the solution MgSO₄

Its' molarity = 1.3 × 10⁻² M

It's ionization equation is;

MgSO₄ → Mg²⁺ + SO₄²⁻

The equation is balanced and so we can say that;

1 mole of MgSO₄ produces 1 mole of Mg²⁺ and 1 mole of  SO₄²⁻.

Thus;

Concentration of Mg²⁺ = 1.3 × 10⁻² M

Concentration of SO₄²⁻ = 1.3 × 10⁻² M

C) We are given the solution C₆H₁₂O₆

Its' molarity = 0.015 M

This solution is called glucose and it remains intact when put in water and as a result, it has ionization of 1.

Thus, the concentration remains 0.015 M.

D) We are given a mixture of;

45 mL of 0.272M NaCl and 65.0 mL of 0.0247M (NH₄)₂CO₃.

Let us first find the number of moles for each substance using the formula;

Number of moles = (molarity × volume)/1000

For NaCl; Number of moles = (0.272 × 45)/1000 = 0.01224 mol

For (NH₄)₂CO₃; Number of moles = (0.0247 × 65)/1000 = 0.0016055 mol

Total volume of solution = 45 + 65 = 100 mL

Molarity of each substance in the solution is gotten from the formula;

Molarity = (Number of moles × 1000)/Total volume

Molarity of NaCl = (0.01224 × 1000)/110 = 0.111 M

Molarity of (NH₄)₂CO₃ =  (0.0016055 × 1000)/110 = 0.0146 M

The ionization of NaCl gives;

NaCl → Na⁺ + Cl⁻

The equation is balanced and so we can say that;

1 mole of NaCl produces 1 mole of Na⁺ and 1 mole of  Cl⁻.

Thus;

Concentration of Na⁺ = 0.111 M

Concentration of Cl⁻ = 0.111 M

The ionization of NaCl gives;

(NH₄)₂CO₃ → 2NH₄⁺ + CO₃⁻²

The equation is balanced and so we can say that;

1 mole of (NH₄)₂CO₃ produces 2 mole of NH₄⁺ and 1 mole of CO₃⁻².

Thus;

Concentration of NH₄⁺ = 0.0146 M

Concentration of CO₃⁻² = 2 × 0.0146 M = 0.0292 M

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