What change would you expect on the rate of the SN2 reaction of 1-iodo-2-methylbutane with cyanide ion if the nucleophile concentration is halved and the alkyl halide concentration is unchanged ?

Respuesta :

Answer:

Rate of reaction will be half of it's initial value

Explanation:

For the given [tex]S_{N}2[/tex] reaction, the rate law is -

[tex]Rate=k[1-iodo-2-methylbutane][CN^{-}][/tex]

Where k is rate constant, [1-iodo-2-methylbutane] is concentration of 1-iodo-2-methylbutane and [tex][CN^{-}][/tex] is concentration of [tex]CN^{-}[/tex]

Here nucleophile is the [tex]CN^{-}[/tex] ion

Initiallly, [tex](Rate)_{initial}=k\times [1-iodo-2-methylbutane]_{initial}\times [CN^{-}]_{initial}[/tex]

When concentration of [tex]CN^{-}[/tex] is halved then-

[tex]Rate=k\times [1-iodo-2-methylbutane]_{initial}\times \frac{[CN^{-}]_{initial}}{2}=\frac{(Rate)_{initial}}{2}[/tex]

So rate of reaction will be half of it's initial value