The pressure of a mixture of acetylene and an excess of hydrogen decreases from 0.100 to 0.042 atm in a vessel of a given volume after the catalyst is introduced, and the temperature is restored to its initial value after the reac- tion reaches completion. What was the mole fraction of acetylene in the original mixture

Respuesta :

Explanation:

The given reaction equation is as follows.

       [tex]C_{2}H_{2}(g) + 2H_{2}(g) \rightarrow C_{2}H_{6}(g)[/tex]

Let us assume that the partial pressure of [tex]C_{2}H_{2}[/tex] be 'x' atm. Hence, the partial pressure of [tex]H_{2}[/tex] = (0.1 - x) atm

And, amount of [tex]H_{2}[/tex] left unreacted is as follows.

           [tex](0.1 - x) - 2 \times x[/tex] = 0.1 - 3x

Now, the pressure of [tex]C_{2}H_{6}[/tex] = partial pressure of reacted [tex]C_{2}H_{2}[/tex] = x

So, the pressure of product will be as follows.

     Pressure of the product = partial pressure of [tex]C_{2}H_{6}[/tex] + partial pressure of unreacted [tex]H_{2}[/tex]

                              0.042 = x + (0.1 - 3x)

                                 2x = 0.058

or,                               x = 0.029 atm

Therefore, mole fraction of [tex]C_{2}H_{2}[/tex] = partial pressure of [tex]\frac{C_{2}H_{2}}{\text{Total pressure of the gas mixture}}[/tex]

                   = [tex]\frac{0.029}{0.1}[/tex]

                   = 0.29

Thus, we can conclude that the mole fraction of acetylene in the original mixture is 0.29.