The decomposition of N2O4 into NO2 has Kp = 2. Some N2O4 is placed into an empty container, and the partial pressure of NO2 at equilibrium is measured to be 0.2 atm. What was the initial pressure in the container prior to decomposition? A) 0.10 atm B) 0.12 atm C) 0.20 atm D) 0.22 atm E) 0.30 atm

Respuesta :

Answer: Option (B) is the correct answer.

Explanation:

Expression for the given decomposition reaction is as follows.

           [tex]N_{2}O_{4} \rightarrow 2NO_{2}[/tex]

Let us assume that x concentration of [tex]N_{2}O_{4}[/tex] is present at the initial stage. Therefore, according to the ICE table,

                    [tex]N_{2}O_{4} \rightarrow 2NO_{2}[/tex]

Initial :               x                   0

Change :       - 0.1        [tex]2 \times 0.1[/tex]

Equilibrium : (x - 0.1)             0.2

Now, expression for [tex]K_{p}[/tex] of this reaction is as follows.

     [tex]K_{p} = \frac{P^{2}_{NO_{2}}}{P_{N_{2}O_{4}}}[/tex]

Putting the given values into the above formula as follows.

          [tex]K_{p} = \frac{P^{2}_{NO_{2}}}{P_{N_{2}O_{4}}}[/tex]

                 [tex]2 = \frac{(0.2)^{2}}{(x - 0.1)}[/tex]

                [tex]2 \times (x - 0.1) = (0.2)^{2}[/tex]

                            x = 0.12

This means that [tex]P_{N_{2}O_{4}}[/tex] = x = 0.12 atm.

Thus, we can conclude that the initial pressure in the container prior to decomposition is 0.12 atm.

We can conclude that the initial pressure in the container before the decomposition of N₂O₄ is 0.12 atm.

What is the decomposition reaction of N₂O₄?

The decomposition of N₂O₄ is determined as follows;

N₂O₄ → 2NO₂

ICE table can be created as follows;

     N₂O₄ → 2NO₂

I:      x            0

C:    0.1        2(0.1)

E: (x - 0.1)    (0.2 - 0)

Expression for equilibrium constant;

[tex]K_p = \frac{P^2NO_2}{PN_2O_4} \\\\2 = \frac{0.2^2}{(x - 0.1)} \\\\2(x - 0.1) = 0.2^2\\\\x-0.1 = 0.02\\\\x = 0.12[/tex]

Thus, we can conclude that the initial pressure in the container before the decomposition of N₂O₄ is 0.12 atm.

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