Determine the boundary work done by a gas during an expansion process if the pressure and volume values at various states are measured to be 300 kPa, 1 L; 290 kPa, 1.1 L; 270 kPa, 1.2 L; 250 kPa, 1.4 L; 220 kPa, 1.7 L; and 200 kPa, 2 L

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Answer:

attached below

Explanation:

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By Riemann sums, the boundary work done by a gas during an expansion process based on the information given by the statement is approximately 0.243 joules.

How to determine the boundary work done by a gas during an expansion process

A process is a consecution of states of a system. The boundary work (W), in kilojoules, is the work done by the system on surroundings and in a P-V diagram this kind of work is equal to the area below the curve, which can be approximated by Riemann sums:

[tex]W = \sum\limits_{i=1}^{n-1} p_{i}\cdot (V_{i+1}-V_{i}) + \frac{1}{2}\sum\limits_{i=1}^{n-1} (p_{i+1}-p_{i})\cdot (V_{i+1}-V_{i})[/tex]     (1)

Where:

  • p - Pressure, in kilopascals.
  • V - Volume, in cubic meters.

[tex]W = \frac{1}{2} \sum\limits_{i=1}^{n-1} (p_{i+1}+p_{i})\cdot (V_{i+1}-V_{i})[/tex]

Now we proceed to calculate the boundary work:

W = 0.5 · [(300 kPa + 290 kPa) · (1.1 × 10⁻³ m³ - 1 × 10⁻³ m³) + (270 kPa + 290 kPa) · (1.2 × 10⁻³ m³ - 1.1 × 10⁻³ m³) + (250 kPa + 270 kPa) · (1.4 × 10⁻³ m³ - 1.2 × 10⁻³ m³) + (220 kPa + 250 kPa) · (1.7 × 10⁻³ m³ - 1.4 × 10⁻³ m³) + (200 kPa + 220 kPa) · (2 × 10⁻³ m³ - 1.7 × 10⁻³ m³)]

W = 0.243 kJ

By Riemann sums, the boundary work done by a gas during an expansion process based on the information given by the statement is approximately 0.243 joules.

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