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KCl has the same structure as NaCl. The length of the unit cell is 628pm. The density of KCl is 1.984 g/cm3, and its formula mass is 74.55 amu. Using this information, calculate Avogadro’s number.

Respuesta :

Answer: The value of Avogadro's number is [tex]6.07\times 10^{23}[/tex]

Explanation:

NaCl crystallizes as face centered cubic, where Z = 4

To calculate the density of metal, we use the equation:

[tex]\rho=\frac{Z\times M}{N_{A}\times a^{3}}[/tex]

where,

[tex]\rho[/tex] = density  of KCl = [tex]1.984g/cm^3[/tex]

Z = number of atom in unit cell = 4  (FCC)

M = atomic mass of KCl = 74.55 g/mol

[tex]N_{A}[/tex] = Avogadro's number = ?

a = edge length of unit cell = [tex]628pm=628\times 10^{-10}cm[/tex]    (Conversion factor:  [tex]1cm=10^{10}pm[/tex]  )

Putting values in above equation, we get:

[tex]1.984=\frac{4\times 74.55}{N_A\times (628\times 10^{-10})^3}\\\\N_A=6.07\times 10^{23}[/tex]

Hence, the value of Avogadro's number is [tex]6.07\times 10^{23}[/tex]