Respuesta :
Answer:
0.830 mL of carbon dioxide will 3.26 g of antacid made of calcium carbonate produce at 37.0 °C and 1.00 atm.
Explanation:
[tex]CaCO_3 (s) + 2 HCl (aq)\rightarrow CaCl_2 (aq) + H_2O (l) + CO_2 (g) [/tex]
Moles of calcium carbonate = 3.26 g
Moles of calcium carbonate = [tex]\frac{3.26 g}{100 g/mol}=0.0326 mol[/tex]
According to reaction, 1 mol of calcium carbonate produces 1 mol of carbon dioxide gas, then 0.0326 moles of calcium carbonate will give :
[tex]\frac{1}{1}\times 0.0326 mol=0.0326 mol[/tex] of carbon dioxide.
Pressure of the gas = P = 1.00 atm
Temperature of the gas = T = 37.0°C = 37.0+ 273 K = 310 K
Volume of the gas = V
Moles of gas = n = 0.0326 mol
[tex]PV=nRT[/tex] ( ideal gas equation )
[tex]V=\frac{nRT}{P}=\frac{0.0326 mol\times 0.0821 atm J/mol K\times 310 K}{1.00 atm}=0.830 mL[/tex]
0.830 mL of carbon dioxide will 3.26 g of antacid made of calcium carbonate produce at 37.0 °C and 1.00 atm.
The volume occupied by the gas at 37.0 °C and 1.00 atm is 0.82 L.
The equation of the reaction is;
CaCO₃ (s) + 2 HCl (aq) → CaCl₂ (aq) + H₂O (l) + CO₂ (g)
Number of moles of carbonate = 3.26 g /100 g/mol = 0.0326 moles
Since 1 mole of carbonate yields 1 mole of carbon dioxide
Hence 0.0326 moles of carbonate yields 0.0326 moles of carbon dioxide
If 1 mole of carbon dioxide occupy 22.4 L at STP
0.0326 moles of carbon dioxide occupies 0.0326 moles × 22.4 L/1 mole
= 0.73 L at STP
At 37.0 °C and 1.00 atm;
T1 = 273 K
P1 = 1 atm
V1 = 0.73 L
T2 = 37.0 °C + 273 = 310 K
P2 = 1 atm
V2 = ?
P1V1/T1 =P2V2/T2
P1V1T2 = P2V2T1
V2 = P1V1T2/P2T1
V2 = 1 atm × 0.73 L × 310 K/1 atm × 273 K
V2 = 0.82 L
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