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"" What is the pH of a solution that is prepared by dissolving 8.52 grams of lactic acid (formula weight = 90.08 grams/mol) and 7.93 grams of sodium lactate (formula weight = 112.06 grams/mole) in water and diluting to 500.00 mL? The Ka for lactic acid is 0.000137.

Respuesta :

Answer: The pH of given solution is 3.74.

Explanation:

The given data is as follows.

 Mass of lactic acid = 8.52 g,    Formula weight of lactic acid = 90.08 g/mol

So, number of moles of lactic acid will be calculated as follows.

   No. of moles = [tex]\frac{mass}{\text{molar mass}}[/tex]

                        = [tex]\frac{8.52 g}{90.08 g/mol}[/tex]

                        = 0.094 moles

   Mass of sodium lactate = 7.93 g,    Formula weight of sodium lactate = 112.06 g/mol

Hence, number of moles of sodium lactate is as follows.

    No. of moles = [tex]\frac{mass}{\text{molar mass}}[/tex]

                        = [tex]\frac{7.93 g}{112.06 g/mol}[/tex]

                         = 0.071 moles

As we know that relation between [tex]K_{a}[/tex] and [tex]pK_{a}[/tex] is as follows.

    [tex]pK_{a} = -log K_{a}[/tex]

                 = -log(0.000137)

                 = 3.86

Using Henderson equation, we will calculate the pH as follows.

      pH = [tex]pK_{a} + log (\frac{\text{Conjugate base}}{\text{Acid}})[/tex]

      pH = [tex]3.86 + log (\frac{\text{sodium lactate}}{\text{lactic acid}})[/tex]

           = [tex]3.86 + log (\frac{0.071}{0.094})[/tex]

            = 3.86 + log (0.755)

            = 3.86 - 0.121

           = 3.74

Therefore, we can conclude that pH of given solution is 3.74.