Argon (Ar) and helium (He) are initially in separate compartments of a container at 25°C. The
Ar in compartment A, which has a volume VA of 6.00 L, has a pressure of 2.00 bar. The He in
compartment B of unknown volume V3 has a pressure of 5.00 bar. When the two compartments
are connected and the gases allowed to mix, the total pressure of gas is 3.60 bar. Assume both
gases behave ideally
(a) [4 marks) Determine the volume of compartment B.
(b) [2 marks] Determine the mole fraction of He in the mixture of gases.

Respuesta :

Answer:

(a) [tex]V_B=11.68L[/tex]

(b) [tex]x_{He}=0.533[/tex]

Explanation:

Hello,

In this case, since the both gases behave ideally, with the given information we can compute the moles of He in A:

[tex]n_A=\frac{0.082\frac{atm*L}{mol*K}*298K}{1.974 atm*6.00L}=2.063mol[/tex]

Thus, since the final pressure is 3.60 bar, we can write:

[tex]P=x_{Ar}P_A+x_{He}P_B\\\\P=\frac{n_{Ar}}{n_{Ar}+n_{He}} P_A+\frac{n_{He}}{n_{Ar}+n_{He}} P_B\\\\3.60bar=\frac{2.063mol}{2.063mol+n_{He}} *2.00bar+\frac{n_{He}}{2.063mol+n_{He}} *5.00bar[/tex]

The moles of helium could be computed via solver as:

[tex]n_{He}=2.358mol[/tex]

Or algebraically:

[tex]3.60bar=\frac{1}{2.063mol+n_{He}} *(4.0126+5.00*n_{He})\\\\7.314+3.60n_{He}=4.013+5.00*n_{He}\\\\7.314-4.013=5.00*n_{He}-3.60n_{He}\\\\n_{He}=\frac{3.3}{1.4}=2.358mol[/tex]

In such a way, the volume of the compartment B is:

[tex]V_B=\frac{n_{He}RT}{P_B}=\frac{2.358mol*0.082\frac{atm*L}{mol*K}*298.15K}{4.935atm}\\ \\V_B=11.68L[/tex]

Finally, he mole fraction of He is:

[tex]x_{He}=\frac{2.358}{2.358+2.063}\\ \\x_{He}=0.533[/tex]

Regards.

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