Determine the vapor pressure of a solution at 25°C that contains 76.6 g of glucose (C6H12O6 ) in 250.0 mL of water. The vapor pressure of pure water at 25°C is 23.8 torr

Respuesta :

Answer:

[tex]23.093\ \text{torr}[/tex]

Explanation:

[tex]M_g[/tex] = Molar mass of glucose = 180.2 g/mol

[tex]M_w[/tex] = Molar mass of water = 18 g/mol

[tex]m_g[/tex] = Mass of glucose = 76.6 g

[tex]m_w[/tex] = Mass of water = [tex]250\times 1\ \text{g/mL}=250\text{g}[/tex]

[tex]P_0[/tex] = Vapor pressure of pure water at 25°C = 23.8 torr

The mole fraction of glucose is

[tex]x_g=\dfrac{\dfrac{m_g}{M_g}}{\dfrac{m_g}{M_g}+\dfrac{m_w}{M_w}}=\dfrac{\dfrac{76.6}{180.2}}{\dfrac{76.6}{180.2}+\dfrac{250}{18}}\\\Rightarrow x_g=0.0297[/tex]

Mole fraction of the solute would be

[tex]\dfrac{P_0-P}{P_0}=x_g\\\Rightarrow 0.0297=\dfrac{23.8-P}{23.8}\\\Rightarrow P=23.8-0.0297\times23.8\\\Rightarrow P=23.093\ \text{torr}[/tex]

The vapor pressure of the solution is [tex]23.093\ \text{torr}[/tex].