Ionic substances are formed by exchange of valencies between the ions that make up the substance.
The ion [tex]Al^3+[/tex] has a valency of +3. It exchanges this valency with other ions as it forms ionic substances.
In the case of OH- which has a valency of 1, the compound Al(OH)3 is formed.
In the case of [tex]S^2-[/tex] which has a valency of 2, the compound Al2S3 is formed.
In the case of [tex]PO4^3-[/tex] which has a valency of 3, the compound AlPO4 is formed.
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