This is an example of classical conditioning, and the library is a conditioned stimulus.
The idea of classical conditioning was first put forward by the man Ivan Pavlov, a Russian physiologist.
In his studies, he was able to successfully associate a once neutral stimulus to a conditioned response. The neutral stimulus hitherto does not produce the expected response until after conditioning has taken place.
In this case, the library was a neutral stimulus. When it becomes associated with a bakery, it provokes the conditioned response of hunger any time you go to the library.
The library is now a conditioned stimulus.
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