g Peroxy acids such as peroxyacetic acid and meta-Chloroperoxybenzoic acid (MCPBA) are good __________ agents and are used in ________ dihydroxylation of alkenes.

Respuesta :

Peroxy acids such as peroxyacetic acid and meta-Chloroperoxybenzoic acid (MCPBA) are good Oxidizing agents and are used in Anti dihydroxylation of alkenes.

Discussion:

Peroxy acids generally are good Oxidizing agents as the name relates to peroxides.

Epoxides are highly stranded three-membered rings which are very reactive toward nucleophilic substitution reactions since they result in opening the ring thus releasing the strain:

The epoxide ring can be opened under acid conditions and this is how the anti-dihydroxylation is achieved. The acid serves as catalyst by converting the oxygen into a better leaving group alcohol.

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