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Taking into account the reaction stoichiometry and molarity, 10.17 mL of 0.32 M H₂C₂O₄ is required to titrate 15.50 mL of 0.21 M Mg(OH)₂.

Reaction stoichiometry

In first place, the balanced reaction is:

H₂C₂O₄ + Mg(OH)₂ → MgC₂O₄ + 2 H₂O

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

  • H₂C₂O₄: 1 moles
  • Mg(OH)₂: 1 mole
  • MgC₂O₄: 1 mole
  • H₂O: 2 moles

Definition of molarity

Molar concentration or molarity is a measure of the concentration of a solute in a solution and indicates the number of moles of solute that are dissolved in a given volume.

The molarity of a solution is calculated by dividing the moles of solute by the volume of the solution:

[tex]Molarity=\frac{number of moles}{volume}[/tex]

Molarity is expressed in units [tex]\frac{moles}{liter}[/tex].

Moles of Mg(OH)₂

In this case, you know:

  • molarity= 0.21 M
  • number of moles= ?
  • volume= 15.50 mL= 0.0155 L (being 1000 mL= 1 L)

Replacing in the definition of molarity:

[tex]0.21 M=\frac{number of moles}{0.0155 L}[/tex]

Solving:

number of moles= 0.21 M× 0.0155 L

number of moles= 0.003255 moles

So, you must titrate 0.003255 moles of Mg(OH)₂.

Moles of H₂C₂O₄ required

The following rule of three can be applied: If by reaction stoichiometry 1 mole of Mg(OH)₂ react with 1 mole of H₂C₂O₄, 0.003255 moles of Mg(OH)₂ react with how many moles of H₂C₂O₄?

[tex]amount of moles of H_{2} C_{2} O_{4} =\frac{0.003255 moles of Mg(OH)_{2} x1 mole of H_{2} C_{2} O_{4}}{1mole of Mg(OH)_{2}}[/tex]

amount of moles of H₂C₂O₄= 0.003255 moles

0.003255 moles of H₂C₂O₄ is required to titrate 15.50 mL of 0.21 M Mg(OH)₂.

Volume of H₂C₂O₄ required

In this case, you know:

  • molarity= 0.32 M
  • number of moles= 0.003255 moles
  • volume= ?

Replacing in the definition of molarity:

[tex]0.32 M=\frac{0.003255 M}{volume}[/tex]

Solving:

0.32 M× volume= 0.003255 moles

volume= 0.003255 moles÷ 0.32 M

volume= 0.01017 L= 10.17 mL (being 1 L= 1000 mL)

Finally, 10.17 mL of 0.32 M H₂C₂O₄ is required to titrate 15.50 mL of 0.21 M Mg(OH)₂.

Learn more about

the reaction stoichiometry:

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molarity:

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