Respuesta :

Colligative properties calculations are used for this type of problem. Calculations are as follows:


ΔT(freezing point)  = (Kf)m
ΔT(freezing point)  = 1.86 °C kg / mol (0.50 mol/kg)
ΔT(freezing point)  = 0.93 °C
Tf - T = 0.93 °C
T = -0.93 °C

Answer:

The expected freezing point of a 0.50 m solution of sodium sulfate is -0.93°C.

Explanation:

[tex]\Delta T_f=K_f\times m[/tex]

where,

[tex]\Delta T_f[/tex] =depression in freezing point =

[tex]K_f[/tex] = freezing point constant

m = molality

we have :

[tex]K_f[/tex] =1.86°C/m ,

m = 0.50 m

[tex]\Delta T_f=1.86^oC\times 0.50 m[/tex]

[tex]\Delta T_f=0.93^oC[/tex]

Freezing point of pure water = T =  0°C

Freezing point of solution = [tex]T_f[/tex]

[tex]\Delta T_f=T-T_f[/tex]

[tex]T_f=T-\Delta T_f=0^oC-0.93^oC=-0.93^oC[/tex]

The expected freezing point of a 0.50 m solution of sodium sulfate is -0.93°C.