The unadjusted trial balance is used before making all the adjustments and the adjusted trial balance is used while adjusting both the sides of the ledger.
Trial Balance refers to the list of all the general and ledger accounts that are compiled into debit and credit columns that are equal.
The major difference between adjusted and unadjusted trial balances is that an adjusted trial balance is a list of accounts and balances that is prepared after period-end adjustments that are recorded and posted whereas an unadjusted one is a list of balances and accounts prepared before any accounting adjustments have been made.
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