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Two-electron or metallic conducting electrodes that are connected by an electrolyte solution that conducts ions.

What are potentiometric measurements?

An electrochemical measurement method is potentiometry. The phrase was first used in relation to possible electrochemical measurement chain determinations. Potentiometer is a tool that measures an electrochemical cell's potential without drawing current or changing the makeup of the cell.

Potentiometric measurement is done to detect the difference in potential between a working (an indicator) electrode and a counter (a reference), using a potentiometer. The working/indicator electrode is called the cathode (right half-cell) and the counter/reference electrode is called an anode(half of a left cell).

A basic galvanic cell may just have one electrolyte isolated from it by a semi-permeable membrane, but a more complex one has two independent half-cells linked together by a salt bridge. An inert electrolyte like potassium sulfate is included in the salt bridge, and its ions will diffuse into each of the individual half-cells to balance the charges that are building up at the electrodes.

I understand the question you are looking for is this:

Potentiometric measurements are based on galvanic electrochemical cells. These types of cells consist of:

  1. two inert metal electrodes to which an electrical potential is applied.
  2. two-electron or metallic conducting electrodes that are connected by an electrolyte solution that conducts ions.
  3. a biological recognition element and a physicochemical transducer, often an electrochemical or optical device.
  4. a polarizable working electrode to which an external voltage is applied with the resulting cathodic or anodic current of the cell being monitored.

Learn more about galvanic electrochemical cells here:

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