The labelled diagram of Daniell cell is as shown below
The half-reactions of oxidation and reduction taking place on electrodes are shown:
Oxidation at anode: Zn(s)→Zn 2+(aq)+2e −
Reduction at cathode: Cu 2+ (aq)+2e − →Cu(s)
A Daniell cell is the best model of a galvanic cell which converts chemical energy into electrical energy. The Daniell cell consists of two electrodes of different metals, Zn and Cu; each electrode is in communication with a solution of its own ion; Zinc sulphate and copper sulphate respectively.
The key difference between Daniell cell and galvanic cell is that Daniell cell operates only copper and zinc as electrodes whereas a galvanic cell can have a mixture of metals as electrodes.
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