For a chemical reaction to be spontaneous only at high temperatures, which conditions must be met?

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22-08-2022
Chemistry

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For a chemical reaction to be spontaneous only at high temperatures, which conditions must be met?

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AarushiAanand AarushiAanand · Answer 1 · 2022-08-26T19:38:19+02:00

According to the Gibbs Free Energy equation, some reactions only occur spontaneously at very high temperatures. At high temperatures, the reaction becomes spontaneous if both the entropy as well as the enthalpy are positive.

Changes in Enthalpy, Entropy, as well as Free Energy, Remember that such temperature in the Gibbs free energy equation would be the Kelvin temperature, and as such, it can only be positive. The reaction will constantly be spontaneous at any and all temperatures when H is negative and S is positive, and G's sign is going to be negative.

If a reaction happens without any outside influence, it has been said to as spontaneous. This reaction can release energy and only takes place in the specific circumstances.

Therefore, At high temperatures, the reaction becomes spontaneous if both the entropy as well as the enthalpy are positive.

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