The pH of the original solution is 7.0.
At 25°C, in pure water [H₃O⁺] = 1.0 × 10⁻⁷ M
HCl after four successive ten-fold dilution = (1.0 × 10⁻⁵ M) × (1/10)⁴
= 1.0 × 10⁻⁹ M
[H₃O⁺] from HCl = 1.0 × 10⁻⁹ M ≪ 1.0 × 10⁻⁷ M
Hence, the pH of solution is almost entirely depends on the dissociation of water.
pH of the original solution = -log(1.0 × 10⁻⁷) = 7.0
Hence, the pH of the original solution is 7.0.
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