The solubility of KCl is 3.7 M at 20°C. Two beakers contain 100. mL of saturated KCl solution: 100. mL of 6.0 M HCl is added to the first beaker and 100. mL of 12 M HCl to the second.(b) What mass, if any, of KCl will precipitate from each beaker?

Respuesta :

0g of KCl will precipitate from each beaker.

Steps

Now, 100 mL of 4M HCl and 100 mL of 3.7M KCl are combined in the first beaker to create a total mole of Cl of (0.4 + 0.37) moles = 0.77 moles.

K+ stays at a total of 0.37 moles.

Total solution volume is equal to (100mL + 100mL)/1000mL, or 200mL, or 0.2L.

Total Cl per Liter = 0.77moles/0.2L = 3.85M Cl

total moles of K+ in a liter = 0.37 moles/0.2 liters = 1.85 million K+

Precipitation cannot occur unless Qsp is more than or equal to Ksp, i.e.  Qsp ≥ Ksp

Qsp = [K][Cl] = [1.85]

No KCl will precipitate in the first beaker because [3.85] = 7.12 is less than 13.69 (Ksp).

Calculating the mass precipitated is not necessary because there is no precipitate.

and the solution is 0g.

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