The value of ΔS° is -0.0469kJ/mol.K for the gaseous reaction of carbon monoxide and chlorine to create phosgene (COCl2).
The expression for the standard change in free energy is:
ΔG°= ΔH°- TΔS°
Where,
ΔG is the change in the Gibbs free energy.
T is the absolute temperature. (T in kelvins)
ΔH is the enthalpy change of the reaction.
ΔG is the change in entropy.
Given :
ΔS° at 298 K (ΔH° = -220kJ/mol and ΔG° = -206kJ/mol )
T=298K
ΔG°= ΔH°- TΔS°
ΔS° = ΔH° - ΔG°/T
= -220 -(-206)/ 298
ΔS° = -0.0469kJ/mol.K
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