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For the gaseous reaction of carbon monoxide and chlorine to form phosgene (COCl₂):(b) Assuming that ΔS° and ΔH° change little with temperature, calculate ΔG° at 450. K.

Respuesta :

ΔG° at 450. K is -198.86kJ/mol

The following is the relationship between  ΔG°,  ΔH, and  ΔS°:

ΔH-T ΔS = ΔG

where  ΔG represents the common Gibbs free energy.

the enthalpy change,  ΔH

The temperature in kelvin is T.

Entropy change is  ΔS.

ΔG° = -206 kJ/mol

ΔH° equals -220 kJ/mol

T = 298 K

Using the formula, we obtain:

-220kJ/mol -T ΔS° = -206kJ/mol

220 kJ/mol +206 kJ/mol =T ΔS°.

-T ΔS = 14 kJ/mol

for ΔS-14/298

ΔS=0.047 kJ/mol.K

450K for the temperature Completing a formula with values

ΔG° = (450K)(-0.047kJ/mol)-220kJ/mol

ΔG° = -220 kJ/mol + 21.14 kJ/mol.

ΔG°=198.86 kJ/mol

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