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Balance each skeleton reaction, use Appendix D to calculate E°cell, and state whether the reaction is spontaneous:(a) Mn²⁺(aq) + Co³⁺(aq) → MnO₂(s) + Co²⁺(aq) [acidic]

Respuesta :

A balanced redox reaction equation from each cell notation is given as

2Mn²⁺ + 2H₂O + 2Co³⁺ ---- 2MnO₂ + 2Co²⁺ + 4H⁺

The above reaction is spontaneous.

What is redox reaction?

The reaction in which both reduction and oxidation reaction take place at the same time is termed as redox reaction.

What is oxidation reaction?

Oxidation reactions are those kind of reaction in which a substance or compound or species looses its electron. In this type of reaction, oxidation state of an element goes on increasing.

What is reduction reaction?

Reduction reaction are those kind of reaction in which a substance or compound or species accept thr electron. In this type of reaction, oxidation state of an element goes on decreasing.

At Cathode:

E°(Mn) = -1. 19V × 2 = -2. 38V

At anode:

E°(Co³⁺) = 1. 8 × 2 = 3.6 V

E°cell = 3.6 + 2.38

= 5.98V

Since, the gibbs free energy of the following reaction is negative. Therefore reaction is spontaneous.

Thus, we concluded that the balanced redox reaction equation from each cell notation is given as

2Mn²⁺ + 2H₂O + 2Co³⁺ ---- 2MnO₂ + 2Co²⁺ + 4H⁺

The above reaction is spontaneous.

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