A thin circular-disk earring 4.00 cm in diameter is plated with a coating of gold 0.25 mm thick from an Au³⁺ bath.(b) How many days does it take to deposit the gold on both sides of the pair of earrings?

Respuesta :

The days it take to deposit the gold on both side of two earring if the current is 0.013 A is 32 days.

Earing is circular disc having radius 4.00 cm and thickness of gold plating is 0.25 mm which means that plating of gold is like cylinder.

Volume of gold on one side

Volume of gold plating = π × (radius) ^2 × width

By substituting all the values, we get

= 3.14 × 4 × 0.025cm

= 0.314 cm^2

Given,

density of gold = 19.3 g/cm^3

Calculation of mass of gold deposited on one side

Density = mass/volume

19.3 = mass/ 0.314

Mass = 19.3 × 0.314

= 6.06 g

Cathode reaction

(Au+3) + 3e- ----- Au

From chemical reaction we noticed that 3 mol. of e- reacts with 1 mol of Au3+ to form 1 mol of Au.

Calculation of charge

Charge passed to deposit 6.06g of gold can be calculated as

6.06 ×3 × 9.65× 10^4/ 196.97

= 8.91 × 10^3 C

Calculation of time

Time = charge/ current

= 8.91 × 10^3 /(0.013 × 3600 × 24)

= 7.93 days.

The time required for plating one side = 8 days

Two earing have four faces

Time for plating four surfaces = 8 × 4

= 32 days.

Thus, we calculated that the days it take to deposit the gold on both side of two earring if the current is 0.013 A is 32 days.

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