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Two bidentate ligands used extensively in analytical chemistry are bipyridyl (bipy) and ortho-phenanthroline (o-phen):Draw structures and discuss the possibility of isomers for(b) [Fe(o-phen)₃]³⁺

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Isomers are compounds that contain exactly the same number of atoms, i.e., they have exactly the same empirical formula, but differ from each other by the way in which the atoms are arranged. Examples of isomers with the formula C8H10 are ethyl benzene, m-xylene, p-xylene, and o-xylene.

How do you identify isomers?

You can tell them apart by their bonding patterns and how they take up three-dimensional space. Identify structural (constitutional) isomers by their bonding patterns. The atoms of the compounds are the same but they are connected in such a way as to make different functional groups.

How isomers are formed?

Two main forms of isomerism are structural or constitutional isomerism, in which bonds between the atoms differ; and stereoisomerism or spatial isomerism, in which the bonds are the same but the relative positions of the atoms differ.

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