500. ml of a solution containing 1.5 m nh3(aq) is mixed with 500. ml of a solution containing 0.50m of hcl(aq). what is the ph of the final solution? (kb(nh3) = 1.8 x 10-5)

Respuesta :

The pH of the final solution is 9.25.

What is pH?

In chemistry the pH scale is used to define the acidity or basicity of an aqueous solution. Historically, pH stood for "potential of hydrogen." The pH values of acidic solutions are typically lower than those of basic or alkaline solutions.

Moles = Molarity * Volume(L)

n(NH3) = 1.5 * 0.5 = 0.75 mol

n(HCl) = 0.5 * 0.5 = 0.25 mol

HCl will react with NH3 to form Nh4Cl which is conjugate acid of NH3, so, they will form buffer solution.

HCl + NH3 --> NH4Cl

n(HCl) = n(NH4Cl)

remaining NH3 = 0.75 - 0.25 = 0.50 mol

Whenever the moles of weak base and its conjugate acid is same in buffer, the pOH is equal to its pkb.

pkb = -log(Kb) = - log (1.8 * 10∧ -5) = 4.745

pkb = pOH = 4.745

pH = 14 - 4.745 = 9.25

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