A 695.7 ng sample of an unknown radioactive substance was placed in storage and its mass measured periodically. After 47 daysthe amount of radioactive substance had decreased to 86.96 ng. How many half-lives of the unknown radioactive substancehave occurred?

Respuesta :

The decay of this radioactive unknown compound is a first-order process.

We can express the time dependence of its mass m using a first-order integrated rate law, where k is the rate constant:

[tex]m_t=m_0xe^{-kxt}[/tex]

mt = mass at time t

m0 = initial mass

t = time

-----------------------------------------------------------------------------------------------------

Procedure:

1) We need to find "k":

From the first-order rate law we clear k,

[tex]\begin{gathered} \frac{m_t}{m_0}=\text{ }e^{-kxt} \\ \ln (\frac{m_t}{m_0})=\text{ -kxt} \\ \frac{\ln (\frac{m_t}{m_0})}{-t}=\text{ k} \end{gathered}[/tex][tex]k\text{ = }\frac{\ln (\frac{86.96ng}{695.7ng})}{-47}=0.044days^{-1}\text{ }[/tex]

----------------------------------------------------------------------------------------------

2) We find the half-life from the value of k we have just calculated:

[tex]t_{\frac{1}{2}}=\text{ }\frac{\ln 2}{k}=\text{ }15.7\text{ days}[/tex]

-----------------------------------------------------------------------------------------------

3) The number of half-lives of the unknown sample is:

Number of Half-lives = 47 days / 15.7 days = 3 (approx.)

Answer: Number of half-lives = 3