Data:
Gas: methane = CH4
V = 2.00 liter
T = 66°C = 66 + 273.15 K = 339.15 K
Use the ideal gas equation pV = n RT
R = 0.082 atm*liter / K*mol
n is the number of moles and is calculated using the molar mass,MM, of CH4.
MM of CH4 = 12.0 g/mol + 4*1 g/mol = 16.0 g / mol
n = mass / MM = 8.60 g / 16.0 g/mol = 0.5375 mol
Now you can use the formula: pV = nRT => p = nRT / V
p = 0.5375 mol * 0.082 atm*liter / K*mol * 339.15 K / 2.00 liter
p = 7.47 atm