H₂CO₃ ⇔ HCO₃⁻ + H⁺
I 0.160 0 0
C -x +x +x
E 0.160-x +x +x
Ka1 = [HCO₃⁻][H⁺] / [H₂CO₃]
4.3 x 10⁻⁷ = x² / (0.160-x) (x is neglected in 0.160-x = 0.160)
x² = 6.88 x 10⁻⁸
x = 2.62 x 10⁻⁴
HCO₃⁻ ⇔ CO₃⁻² + H⁺
I 2.62 x 10⁻⁴ 0 2.62 x 10⁻⁴
C -x +x +x
E 2.62 x 10⁻⁴ - x +x 2.62 x 10⁻⁴ + x
Ka2 = [CO₃⁻²][H⁺] / [HCO₃⁻]
5.6 x 10⁻¹¹ = x(2.62 x 10⁻⁴ + x) / (2.62 x 10⁻⁴ - x)
x = 5.6 x 10⁻¹¹
Thus,
[H₂CO₃] = 0.160 - (2.62 x 10⁻⁴) = 0.16 M
[HCO₃⁻] = 2.62 x 10⁻⁴ - ( 5.6 x 10⁻¹¹) = 2.6 x 10⁻⁴ M
[CO₃⁻²] = 5.6 x 10⁻¹¹ M
[H₃O⁺] = 2.62 x 10⁻⁴ + 5.6 x 10⁻¹¹ = 2.6 x 10⁻⁴ M
[OH⁻] = 3.8 x 10⁻¹¹
