Respuesta :
A) Pure water (assume that the pH is 7.0 and remains constant).
[OH-] = 10⁻⁷
[Fe(3+)] = 4.0x10⁻³⁸/[OH-]³ = 4.0x10⁻¹⁷ (M)
That means the solubility is 4.0x10⁻¹⁷ mol/L.
(B) A solution buffered at pH = 5.0.
[OH-] = 10⁻⁹
[Fe(3+)] = 4.0x10⁻³⁸/[OH-]³ = 4.0x10⁻¹¹ (M)
That means the solubility is 4.0x10⁻¹¹ mol/L.
(C) A solution buffered at pH = 11.0.
[OH-] = 10⁻³
[Fe(3+)] = 4.0x10⁻³⁸/[OH-]³ = 4.0x10⁻²⁹ (M)
That means the solubility is 4.0x10⁻²⁹ mol/L.
[OH-] = 10⁻⁷
[Fe(3+)] = 4.0x10⁻³⁸/[OH-]³ = 4.0x10⁻¹⁷ (M)
That means the solubility is 4.0x10⁻¹⁷ mol/L.
(B) A solution buffered at pH = 5.0.
[OH-] = 10⁻⁹
[Fe(3+)] = 4.0x10⁻³⁸/[OH-]³ = 4.0x10⁻¹¹ (M)
That means the solubility is 4.0x10⁻¹¹ mol/L.
(C) A solution buffered at pH = 11.0.
[OH-] = 10⁻³
[Fe(3+)] = 4.0x10⁻³⁸/[OH-]³ = 4.0x10⁻²⁹ (M)
That means the solubility is 4.0x10⁻²⁹ mol/L.
Answer:
The molar solubility of Fe(OH)₃ in pure water is 2.0x10⁻¹⁰ M.
Explanation:
First, remember that the molar solubility of a compound is the maximum molar concentration of solute in a specific solvent. In this case, the solute is Fe(OH)₃ and the solvent is water.
- To calculate the molar solubility of a compound, we have to start by writing the dissociation reaction and make sure it is balanced. You can check the attachment for better understanding.
- The molar solubility of each dissociated species is represented by the letter "s" and multiply by its coefficient.
- The molar solubility is calculated from the Ksp of a compound. The Ksp is the Solubility Product Constant, so we have to make the product of molar solubility of each specie:
Kps = [Fe⁺³].[OH⁻]³
It is very important to raise to the power indicated by the coefficient the solubility of each specie when we write it in the Ksp equation.
After a few mathematical steps for clearing the solubility "s" we find that the result is 1.96x10⁻¹⁰ M that it is approximately to 2.0x10⁻¹⁰ M.
Note:
The molar solubility has units of molarity which is represented in chemistry by capital letter M not small letter m. Small letter m represents molality in chemistry. Molarity and molality are differents, be careful.
