The ML of 0.85 m NaOH required to titrate 25 ml of 0.72m hbr to the equivalence point is calculated as follows
calculate the moles of HBr used
moles = molarity x volume
25 x0.072/1000= 0.0018 moles
write the equation for reaction
NaOH + HBr = NaBr + H2O
from reacting equation the mole ratio between NaOH to HBr is 1:1 therefore the moles of NaOH = 0.0018 moles
volume = moles/molarity
0.0018/0.085 = 0.021 L in Ml = 0.021 x1000=21.18 Ml ofNaOH