For the reaction o(g) + o2(g) → o3(g) δh o = −107.2 kj/mol given that the bond enthalpy in o2(g) is 498.7 kj/mol, calculate the average bond enthalpy in o3.

Respuesta :

The reaction;
O(g) +O2(g)→O3(g), ΔH = sum of bond enthalpy of reactants-sum of food enthalpy of products.
ΔH = ( bond enthalpy of O(g)+bond enthalpy of O2 (g) - bond enthalpy of O3(g)
-107.2 kJ/mol = O+487.7kJ/mol =O+487.7 kJ/mol +487.7kJ/mol =594.9 kJ/mol
Bond enthalpy (BE) of O3(g) is equals to 2× bond enthalpy of O3(g) because, O3(g) has two types of bonds from its lewis structure (0-0=0).
∴2BE of O3(g) = 594.9kJ/mol
Average bond enthalpy = 594.9kJ/mol/2
=297.45kJ/mol
∴ Averange bond enthalpy of O3(g) is 297.45kJ/mol.

The  average bond enthalpy in ozone is 303.0 KJ/mol .

Given here,

The change of enthalpy  - 107.2 kJ/mo

BE of O2 -  498.7 kJ/mol

The reaction

[tex]\rm \bold{ O(g) +O_2(g)\rightarrow O_3(g)}[/tex]

the change of enthalpy of reaction

 H= (BE reactants) - (BE products)

-107.2KJ/mol= 498.7 kJ/mol- (bond enthalpy of products (BE)

The bond enthalpy of Ozone  2 times the bonding enthaply of products Because there's 2 kinds of bonds  in O3

605.9 KJ/mol = 2BE

BEproducts = 303.0 KJ/mol

Hence, we can conclude that the  average bond enthalpy in ozone is 303.0 KJ/mol .

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