Calculate the pH of a solution prepared by dissolving 0.150 mol of benzoic acid and 0.300 mol of sodium benzoate in water sufficient to yield 1.00 L of solution. The Ka of benzoic acid is 6.30 × 10-5.

Respuesta :

Answer : The pH of a solution is, 4.50

Explanation : Given,

[tex]K_a=6.30\times 10^{-5}[/tex]

Concentration of benzoic acid (Acid) = 0.150 M

Concentration of sodium benzoate (salt) = 0.300 M

First we have to calculate the value of [tex]pK_a[/tex].

The expression used for the calculation of [tex]pK_a[/tex] is,

[tex]pK_a=-\log (K_a)[/tex]

Now put the value of [tex]K_a[/tex] in this expression, we get:

[tex]pK_a=-\log (6.30\times 10^{-5})[/tex]

[tex]pK_a=5-\log (6.30)[/tex]

[tex]pK_a=4.20[/tex]

Now we have to calculate the pH of buffer.

Using Henderson Hesselbach equation :

[tex]pH=pK_a+\log \frac{[Salt]}{[Acid]}[/tex]

Now put all the given values in this expression, we get:

[tex]pH=4.20+\log (\frac{0.300}{0.150})[/tex]

[tex]pH=4.50[/tex]

Thus, the pH of a solution is, 4.50

The pH of the solution prepared by benzoic acid and sodium benzoate has been 4.5.

The [tex]\rm \bold{pK_a}[/tex] of the solution has been calculated based on the [tex]\rm \bold{k_a}[/tex] value.

[tex]\rm \bold{pK_a}[/tex] = -log  [tex]\rm \bold{k_a}[/tex]

Given,  [tex]\rm \bold{k_a}[/tex] = 6.30 [tex]\rm \times\;10^-^5[/tex]

[tex]\rm \bold{pK_a}[/tex] = -log (6.30 [tex]\rm \times\;10^-^5[/tex])

[tex]\rm \bold{pK_a}[/tex] = 4.20

The pH of the solution can be given by:

pH = [tex]\rm pk_a\;+\;log\;\dfrac{[salt]}{[acid]}[/tex]

The salt has been the sodium benzoate with a concentration of 0.30 mol.

The concentration of acid (benzoic acid) has been 0.150 mol.

Substituting the values:

pH = 4.20 + [tex]\rm log\;\dfrac{0.3}{0.15}[/tex]

pH = 4.20 + log 2

pH = 4.20 + 0.30

pH = 4.5

The pH of the solution prepared by benzoic acid and sodium benzoate has been 4.5.

For more information about the pH of the solution, refer to the link:

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