A saturated solution of barium fluoride, BaF2BaF2, was prepared by dissolving solid BaF2BaF2 in water. The concentration of Ba2+Ba2+ ion in the solution was found to be 7.52×10−3 MM . Calculate KspKspK_sp for BaF2BaF2.

Respuesta :

Answer: [tex]1.70\times 10^{-6}[/tex]

Explanation:

Solubility product is defined as the equilibrium constant in which a solid ionic compound is dissolved to produce its ions in solution. It is represented as

The equation for the ionization of the [tex]BaF_2[/tex] is given as:

[tex]BaF_2\rightarrow Ba^{2+}+2F^-[/tex]

When the solubility of [tex]BaF_2[/tex] is S moles/liter, then the solubility of [tex]Ba^{2+}[/tex]  will be S moles/liter and solubility of [tex]F^-[/tex] will be 2S moles/liter.

By stoichiometry of the reaction:

1 mole of [tex]BaF_2[/tex] gives 1 mole of [tex]Ba^{2+[/tex] and 2 moles of [tex]F^-[/tex]

[tex]K_{sp}=[Ba^{2+}][F^{-}]^2[/tex]

[tex]K_{sp}=s\times (2s)^2[/tex]

[tex]K_{sp}=4\times (7.52\times 10^{-3})^3[/tex]

[tex]K_{sp}=1.70\times 10^{-6}[/tex]

Thus [tex]K_{sp}[/tex] for [tex]BaF_2[/tex] is [tex]1.70\times 10^{-6}[/tex]