Respuesta :
It is a good thing that you already have answered the first question. Now, moving on to the second question, there exist an equation for the neutralization of acid by a base that is shown below,
M₁V₁ = M₂V₂
Now, all the variables in the equation are given except for our unknown which is the V₂. Substituting the known values from the given above,
(0.1 M)(25 mL) = (0.05 M)(V₂)
The value of V₂ from the equation above is 50 mL. Therefore, 50 mL of 0.05 M NaOH solution will be needed to completely react with HNO3.
M₁V₁ = M₂V₂
Now, all the variables in the equation are given except for our unknown which is the V₂. Substituting the known values from the given above,
(0.1 M)(25 mL) = (0.05 M)(V₂)
The value of V₂ from the equation above is 50 mL. Therefore, 50 mL of 0.05 M NaOH solution will be needed to completely react with HNO3.
Taking into account the definition of molarity and reaction stoichiometry:
- there are 0.0025 moles of HNO₃ in the sample.
- the volume of 0.0500 M NaOH solution required to completely react with the HNO₃ is 50 mL.
Definition of molarity
Molar concentration or molarity is a measure of the concentration of a solute in a solution and indicates the number of moles of solute that are dissolved in a given volume.
The molarity of a solution is calculated by dividing the moles of solute by the volume of the solution:
[tex]Molarity=\frac{number of moles}{volume}[/tex]
Molarity is expressed in units [tex]\frac{moles}{liter}[/tex].
Moles of HNO₃ in the sample
In this case, you have a 25 mL sample of 0.100 M HNO₃. Being 1000 mL=1 L, then 25 mL= 0.025 L.
Replacing in the definition of molarity:
[tex]0.100 M=\frac{number of moles}{0.025 L}[/tex]
Solving:
number of moles= 0.100 M×0.025 L
number of moles= 0.0025 moles
Finally, there are 0.0025 moles of HNO₃ in the sample.
Reaction stoichiometry
The balanced reaction is:
HNO₃ + NaOH ⟶ NaNO₃ + H₂O
By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:
- HNO₃: 1 mole
- NaOH: 1 mole
- NaNO₃: 1 mole
- H₂O: 1 mole
Volume of 0.0500 M NaOH solution required
You can apply the following rule of three: If by reaction stoichiometry 1 mole of HNO₃ reacts with 1 mole of NaOH, 0.0025 moles of HNO₃ react with how many moles of NaOH?
[tex]amount of moles of NaOH=\frac{0.0025 moles of HNO_{3}x1 mole of NaOH }{1 mole of HNO_{3}}[/tex]
amount of moles of NaOH= 0.0025 moles
You have a 0.0500 M NaOH solution. Replacing in the definition og molarity:
[tex]0.0500 M=\frac{0.0025 moles}{volume}[/tex]
0.0500 M×volume= 0.0025 moles
volume= 0.0025 moles÷ 0.0500 M
volume= 0.05 L= 50 mL
Finally, the volume of 0.0500 M NaOH solution required to completely react with the HNO₃ is 50 mL.
Learn more about
molarity:
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reaction stoichiometry
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